Last Updated :2024/12/19
Researcher Information
Degree
Research Keyword
Career
- Apr. 2022 - Present
兵庫医科大学 薬学部 教授 - Apr. 2007 - Mar. 2022
兵庫医療大学 薬学部 教授 - Aug. 2004 - Mar. 2007
京都大学大学院 薬学研究科 助教授 - Apr. 2002 - Jul. 2004
Kyoto University, Graduate School of Pharmaceutical Sciences - Apr. 2001 - Mar. 2002
Kobe Pharmaceutical University - Feb. 2001 - Jan. 2002
米国ノースダコタ州立大学 日本学術振興会海外特別研究員 - Apr. 1996 - Mar. 2001
Kobe Pharmaceutical University
Research activity information
Award
Paper
- Intramolecular Cyclopropanation of Active Methylene Derivatives Based on FeCl2 or FeCl3‐Promoted Radical‐Polar Crossover Reactions
Eito Yoshioka; Yuuki Imoto; Yousuke Yamaoka; Tomoko Ikeda; Hiroki Takahashi; Ryousuke Tanaka; Naoki Hayashi; Hideto Miyabe
Chemistry – A European Journal, Apr. 2024, [Reviewed] - NHC-Catalyzed Reaction of Aldehydes for C(sp2)–O Bond Formation
Yousuke Yamaoka; Hideto Miyabe
Catalysts, Mar. 2024, [Reviewed], [Invited] - Regiocontrol Using Fluoro Substituent on 3,6-Disubstituted Arynes
Eito Yoshioka; Yousuke Yamaoka; Shunsuke Shimada; Hikaru Tanaka; Hideto Miyabe
Chemical and Pharmaceutical Bulletin, Oct. 2023, [Reviewed] - N-Heterocyclic Carbene Catalyzed Cross Dehydrogenative Coupling of Aldehydes with Methanol: Combined Use of Eosin Y and Hexachloroethane
Hideto Miyabe; Eito Yoshioka; Hiroki Takahashi; Akane Kubo; Miki Ohno; Fuuka Watanabe; Rino Shiono; Yuuki Miyazaki
Synthesis, Aug. 2022, [Reviewed] - Regiocontrol by Halogen Substituent on Arynes: Generation of 3-Haloarynes and Their Synthetic Reactions
Hideto Miyabe
Synthesis, Apr. 2022, [Reviewed], [Invited] - Oxidation of α,β-Unsaturated Ketones by Organophotocatalysis Using Rhodamine 6G under Visible Light Irradiation: Insight into the Reaction Mechanism
Eito Yoshioka; Hiroki Takahashi; Hideto Miyabe; Hikari Wanibe; Yukina Hontani; Kouki Hatsuse; Remi Shimizu; Akira Kawashima; Shigeru Kohtani
Synthesis, Sep. 2021, [Reviewed] - Aryne-Mediated Synthesis of Oxygen Heterocycles and Application to Cysteine-Selective Trapping
Hideto Miyabe
HETEROCYCLES, 2021, [Reviewed], [Invited] - Aryne Precursors for Selective Generation of 3-Haloarynes: Preparation and Application to Synthetic Reactions
Eito Yoshioka; Kengo Kakigi; Shouta Miyoshi; Yuichi Kawasaki; Hideto Miyabe
The Journal of Organic Chemistry, Sep. 2020, [Reviewed] - Synthesis of Oxygen-Heterocycles Having Linker Components for Trapping Cysteine Derivatives
Hideto Miyabe; Eito Yoshioka; Ikko Minato; Hideki Takashima
HETEROCYCLES, 2020, [Reviewed], [Invited] - Photocatalytic single electron transfer reactions on TiO2 semiconductor
Hideto Miyabe; Shigeru Kohtani
Science China Chemistry, Oct. 2019, [Reviewed], [Invited] - Stereoselective Organic Reactions in Heterogeneous Semiconductor Photocatalysis
Shigeru Kohtani; Akira Kawashima; Hideto Miyabe
Frontiers in Chemistry, Sep. 2019, [Reviewed] - 価数制御した希土類ナノ結晶の発光特性評価
岩本 真帆; 神田 翔太; 川島 祥; 宮部 豪人; 長谷川 靖哉; 甲谷 繁
日本薬学会年会要旨集, Mar. 2019 - Transition-Metal-Free Activation of Amide Bond by Arynes
Hideto Miyabe
Molecules, Aug. 2018, [Reviewed], [Invited] - Oxidative Functionalization of Cinnamaldehyde Derivatives: Control of Chemoselectivity by Organophotocatalysis and Dual Organocatalysis
Eito Yoshioka; Maika Inoue; Yuka Nagoshi; Ayumi Kobayashi; Rumiko Mizobuchi; Akira Kawashima; Shigeru Kohtani; Hideto Miyabe
The Journal of Organic Chemistry, Jul. 2018, [Reviewed] - Chiral α-hydroxy acid-coadsorbed TiO2photocatalysts for asymmetric induction in hydrogenation of aromatic ketones
Shigeru Kohtani; Akira Kawashima; Fumie Masuda; Momono Sumi; Yuichi Kitagawa; Eito Yoshioka; Yasuchika Hasegawa; Hideto Miyabe
Chemical Communications, 2018, [Reviewed] - Aqueous-Medium Selective Modification of Cysteine and Related Thiols with Tricyclic Oxygen-Heterocycles
Eito Yoshioka; Yuya Goto; Ikko Minato; Hideto Miyabe
SYNTHESIS-STUTTGART, Nov. 2017, [Reviewed] - Reactivity of Trapped and Accumulated Electrons in Titanium Dioxide Photocatalysis
Shigeru Kohtani; Akira Kawashima; Hideto Miyabe
CATALYSTS, Oct. 2017, [Reviewed] - Unique Strategies for Controlling Enantioselective Stereochemistry of Cyclizations via Radical Intermediates
Hideto Miyabe
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Jun. 2017, [Reviewed] - Progress in Enantioselective Radical Cyclizations
Hideto Miyabe; Akira Kawashima; Eito Yoshioka; Shigeru Kohtani
CHEMISTRY-A EUROPEAN JOURNAL, May 2017, [Reviewed], [Invited] - Iron(III) Chloride Promoted Oxidative Radical Cyclization for the Synthesis of Lactams Having a Quaternary Carbon
Eito Yoshioka; Yuuki Imoto; Tomohiro Yoshikawa; Shigeru Kohtani; Hideto Miyabe
SYNLETT, Apr. 2017, [Reviewed] - Oxidative Radical Cyclization–Cyclization Reaction Leading to 1H-Benzo[f]isoindole Derivatives
Eito Yoshioka; Hideto Miyabe
Molbank, Feb. 2017, [Reviewed], [Invited] - Photo-Induced Atom-Transfer Radical Reactions Using Charge-Transfer Complex between Iodine and Tertiary Amine
Eito Yoshioka; Shigeru Kohtani; Takurou Hashimoto; Tomoko Takebe; Hideto Miyabe
CHEMICAL & PHARMACEUTICAL BULLETIN, Jan. 2017, [Reviewed] - Aqueous-Medium Carbon-Carbon Bond-Forming Radical Reactions Catalyzed by Excited Rhodamine B as a Metal-Free Organic Dye under Visible Light Irradiation
Eito Yoshioka; Shigeru Kohtani; Takahisa Jichu; Takuya Fukazawa; Toyokazu Nagai; Akira Kawashima; Yoshiji Takemoto; Hideto Miyabe
JOURNAL OF ORGANIC CHEMISTRY, Aug. 2016, [Reviewed] - Photoreductive transformation of fluorinated acetophenone derivatives on titanium dioxide: Defluorination vs. reduction of carbonyl group
Shigeru Kohtani; Takuya Kurokawa; Eito Yoshioka; Hideto Miyabe
APPLIED CATALYSIS A-GENERAL, Jul. 2016, [Reviewed] - Research and Development of Domino Radical Cyclization Reactions
Hideto Miyabe; Eito Yoshioka; Shigeru Kohtani
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Sep. 2015, [Reviewed], [Invited] - Photohydrogenation of Acetophenone Using Coumarin Dye-Sensitized Titanium Dioxide under Visible Light Irradiation
Shigeru Kohtani; Mizuho Mori; Eito Yoshioka; Hideto Miyabe
Catalysts, Aug. 2015, [Reviewed] - Multicomponent Coupling Reaction Using Arynes: Synthesis of Xanthene Derivatives
Eito Yoshioka; Masatoshi Nishimura; Takashi Nakazawa; Shigeru Kohtani; Hideto Miyabe
JOURNAL OF ORGANIC CHEMISTRY, Aug. 2015, [Reviewed] - Synthesis of Oxygen Heterocycles via Aromatic C-O Bond Formation Using Arynes
Hideto Miyabe
MOLECULES, Jul. 2015, [Reviewed], [Invited] - Carbon radical addition-cyclization reaction induced by ruthenium-photocatalyst under visible light irradiation
Eito Yoshioka; Shigeru Kohtani; Eri Tanaka; Yukari Hata; Hideto Miyabe
TETRAHEDRON, Feb. 2015, [Reviewed] - 2,3,4,9-Tetrahydro-9-(3-hydroxy-1,4-dioxo-1H-dihydro-naphthalen-2-yl)-8-methoxy-3,3-dimethyl-1H-xanthen-1-one
Eito Yoshioka; Shigeru Kohtani; Hideto Miyabe
Molbank, Jan. 2015, [Reviewed], [Invited] - Insertion of Arynes into the pi-Bond Giving [2+2] Cycloaddition-type Adducts
Hideto Miyabe
CURRENT ORGANIC CHEMISTRY, 2015, [Reviewed] - Direct Photoinduced Electron Transfer from Excited State of Rhodamine B for Carbon-Radical Generation
Eito Yoshiokaa; Shigeru Kohtani; Takahisa Jichu; Takuya Fukazawa; Toyokazu Nagai; Yoshiji Takemoto; Hideto Miyabe
SYNLETT, Jan. 2015, [Reviewed] - Titanium dioxide-induced photoctalytic reduction for organic synthesis
Shigeru Kohtani; Hideto Miyabe
Titanium Dioxide: Chemical Properties, Applications and Environmental Effects, Jul. 2014 - [4+2] cycloaddition of intermediates generated from arynes and DMF
Eito Yoshioka; Hirofumi Tamenaga; Hideto Miyabe
TETRAHEDRON LETTERS, Feb. 2014, [Reviewed] - Carbonyl and Imine Activation
H. Miyabe; Y. Takemoto
Comprehensive Organic Synthesis: Second Edition, 2014 - Dye-sensitized photo-hydrogenation of aromatic ketones on titanium dioxide under visible light irradiation
Shigeru Kohtani; Saki Nishioka; Eito Yoshioka; Hideto Miyabe
Catalysis Communications, Jan. 2014, [Reviewed] - Kinetic study on photocatalytic hydrogenation of acetophenone derivatives on titanium dioxide
Shigeru Kohtani; Yuna Kamoi; Eito Yoshioka; Hideto Miyabe
CATALYSIS SCIENCE & TECHNOLOGY, 2014, [Reviewed] - Three-Component Coupling Reactions of Arynes for the Synthesis of Benzofurans and Coumarins
Eito Yoshioka; Shigeru Kohtani; Hideto Miyabe
MOLECULES, Jan. 2014, [Reviewed] - Cascade radical reactions via carbon-carbon/heteroatom bond-forming process
Miyabe, H; Takemoto, Y
Universal Organic Chemistry, 2014, [Reviewed] - Straightforward Synthesis of Dihydrobenzofurans and Benzofurans from Arynes
Eito Yoshioka; Hidekazu Tanaka; Shigeru Kohtani; Hideto Miyabe
ORGANIC LETTERS, Aug. 2013, [Reviewed] - Photocatalytic Cascade Carbon-Carbon Bond-Forming Radical Reaction in Aqueous Media
Shigeru Kohtani; Hideto Miyabe; Eito Yoshioka; Eri Tanaka
Synlett, Jun. 2013, [Reviewed] - Cascade radical reaction of substrates with a carbon-carbon triple bond as a radical acceptor
Hideto Miyabe; Ryuta Asada; Yoshiji Takemoto
Beilstein Journal of Organic Chemistry, Jun. 2013, [Reviewed] - Polarity-mismatched addition of electrophilic carbon radicals to an electron-deficient acceptor: Cascade radical addition-cyclization-trapping reaction
Eito Yoshioka; Shigeru Kohtani; Kaori Sawai; Kentefu; Eri Tanaka; Hideto Miyabe
Journal of Organic Chemistry, Oct. 2012, [Reviewed] - Adsorptive and kinetic properties on photocatalytic hydrogenation of aromatic ketones upon UV irradiated polycrystalline titanium dioxide: Differences between acetophenone and its trifluoromethylated derivative
Shigeru Kohtani; Eito Yoshioka; Kenji Saito; Akihiko Kudo; Hideto Miyabe
Journal of Physical Chemistry C, Aug. 2012, [Reviewed] - Inter- and Intramolecular Carbon-Carbon Bond-Forming Radical Reactions
Hideto Miyabe
SYNLETT, Jul. 2012, [Reviewed], [Invited] - Photocatalytic Hydrogenation on Semiconductor Particles
Shigeru Kohtani; Eito Yoshioka; Hideto Miyabe
hydrogenation, 2012, [Reviewed] - Insertion of arynes into the carbon-oxygen double bond of amides and its application into the sequential reactions
Eito Yoshioka; Hideto Miyabe
TETRAHEDRON, Jan. 2012, [Reviewed] - Lewis acid-mediated radical cyclization: stereocontrol in cascade radical addition-cyclization-trapping reactions
Hideto Miyabe; Ryuta Asada; Yoshiji Takemoto
ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, [Reviewed] - A multicomponent coupling reaction induced by insertion of arynes into the C=O bond of formamide
Eito Yoshioka; Shigeru Kohtani; Hideto Miyabe
Angewandte Chemie - International Edition, Jul. 2011, [Reviewed] - Regio- and Enantioselective Allylic Substitution with Less Active N- or O-Nucleophiles Catalyzed by Iridium-Complex of Bis(oxazolinyl)pyridine
Hideto Miyabe; Katsuhiko Moriyama; Yoshiji Takemoto
CHEMICAL & PHARMACEUTICAL BULLETIN, Jun. 2011, [Reviewed] - Expression and function of PD-1 in human γδ T cells that recognize phosphoantigens
Masashi Iwasaki; Yoshimasa Tanaka; Hirohito Kobayashi; Kaoru Murata-Hirai; Hideto Miyabe; Tomoharu Sugie; Masakazu Toi; Nagahiro Minato
European Journal of Immunology, Feb. 2011, [Reviewed] - Cascade radical reaction induced by polarity-mismatched perfluoroalkylation
Eito Yoshioka; Kentefu; Xin Wang; Shigeru Kohtani; Hideto Miyabe
Synlett, 2011, [Reviewed] - Photocatalytic hydrogenation of acetophenone derivatives and diaryl ketones on polycrystalline titanium dioxide
Shigeru Kohtani; Eito Yoshioka; Kenji Saito; Akihiko Kudo; Hideto Miyabe
Catalysis Communications, Jul. 2010, [Reviewed] - Indium(I)-Mediated Radical Carbon-Carbon Bond-Forming Reaction in Aqueous Media
Masafumi Ueda; Hideto Miyabe; Masafumi Torii; Takahiro Kimura; Okiko Miyata; Takeaki Naito
SYNLETT, Jun. 2010, [Reviewed] - Sequential reaction of arynes via insertion into the π-bond of amides and trapping reaction with dialkylzincs
Eito Yoshioka; Shigeru Kohtani; Hideto Miyabe
Organic Letters, May 2010, [Reviewed] - Asymmetric carbon-heteroatom bond-forming reactions
Y. Takemoto; H. Miyabe
Catalytic Asymmetric Synthesis: Third Edition, 2010, [Reviewed] - Progress in intermolecular carbon radical addition to imine derivatives
Hideto Miyabe; Eito Yoshioka; Shigeru Kohtani
Current Organic Chemistry, 2010, [Reviewed], [Invited] - Synthesis of fluorinated imines by addition of fluoroalkyl radicals to conjugated imines
Ueda M; Iwasada E; Miyabe H; Miyata O; Naito T
Synthesis, 2010, [Reviewed] - Aerobic Hydroxylation of N-Borylenamine: Triethylborane-Mediated Hydroxyalkylation of alpha,beta-Unsaturated Oxime Ether
Masafumi Ueda; Hideto Miyabe; Takahiro Kimura; Eiko Kondoh; Takeaki Naito; Okiko Miyata
ORGANIC LETTERS, Oct. 2009, [Reviewed] - ASYMMETRIC SYNTHESIS OF 4-SUBSTITUTED 2,6-DIOXOPIPERIDINE-3-CARBONITRILE BY USING THIOUREA-CATALYZED ASYMMETRIC MICHAEL ADDITION
Tsubasa Inokuma; Yuuki Nagamoto; Shota Sakamoto; Hideto Miyabe; Kiyosei Takasu; Yoshiji Takemoto
HETEROCYCLES, Apr. 2009, [Reviewed], [Invited] - Palladium- or Iridium-Catalyzed Allylic Substitution of Guanidines: Convenient and Direct Modification of Guanidines (vol 74, pg 308, 2009)
Hideto Miyabe; Kazumasa Yoshida; Valluru Krishna Reddy; Yoshiji Takemoto
JOURNAL OF ORGANIC CHEMISTRY, Feb. 2009, [Reviewed] - Synthesis of Heterocycles Using Allylic Substitution with Heteroatom Nucleophiles
Eito Yoshioka; Shigeru Kohtani; Hideto Miyabe
Trends in Heterocyclic Chemistry, 2009, [Reviewed], [Invited] - Enantioselective radical cyclization for the synthesis of cyclic compounds
Eito Yoshioka; Shigeru Kohtani; Hideto Miyabe
Heterocycles, 2009, [Reviewed], [Invited] - Carbon radical addition to N-sulfonylimines mediated by triethylborane or zinc
Ueda M; Miyabe H; Miyata O; Naito T
Tetrahedron, 2009, [Reviewed] - Synthesis of chiral oxime ethers based on regio- and enantioselective allylic substitution catalyzed by iridium-pybox complex
H. Miyabe; A. Matsumura; K. Yoshida; Y. Takemoto
Tetrahedron, 2009, [Reviewed] - Palladium- or iridium-catalyzed allylic substitution of guanidines: Convenient and direct modification of guanidines
H. Miyabe; K. Yoshida; V.K. Reddy; Y. Takemoto
Journal of Organic Chemistry, 2009, [Reviewed] - Intermolecular Carbon Radical Addition to Cyclic Nitrone
Takeaki Naito; Masafumi Ueda; Hideto Miyabe; Nami Nonoguchi; Okiko Miyata; Osamu Tamura
HETEROCYCLES, 2009, [Reviewed] - Discovery and application of asymmetric reaction by multi-functional thioureas
Hideto Miyabe; Yoshiji Takemoto
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, Jul. 2008, [Reviewed], [Invited] - Enantioselective synthesis of [1,2]-oxazinone scaffolds and [1,2]-oxazine core structures of FR900482
Valluru Krishna Redd; Hideto Miyabe; Masashige Yamauchi; Yoshiji Takemoto
TETRAHEDRON, Feb. 2008, [Reviewed] - Loading effects of silver oxides upon generation of reactive oxygen species in semiconductor photocatalysis
Shigeru Kohtani; Kazuhiro Yoshida; Toshiyasu Maekawa; Akihide Iwase; Akihiko Kudo; Hideto Miyabe; Ryoichi Nakagaki
Physical Chemistry Chemical Physics, 2008, [Reviewed] - Regioselective hydroxysulfenylation of α,β-unsaturated imines: Enhanced stability of an intermediate radical
Ueda M; Miyabe H; Shimizu H; Sugino H; Miyata O; Naito T
Angewandte Chemie - International Edition, 2008, [Reviewed] - Methyl, Ethyl-, and text-Butyl-2-[(diphenylmethylene)amino]-2-propenate
Hideto Miyabe
Encyclopedia of Reagents for Organic Synthesis, Sep. 2007, [Reviewed], [Invited] - Chiral-thiourea-catalyzed direct Mannich reaction
Yousuke Yamaoka; Hideto Miyabe; Yoshizurm Yasui; Yoshiji Takemoto
SYNTHESIS-STUTTGART, Aug. 2007, [Reviewed] - Enantioselective cascade radical addition-cyclization of oxime ethers
Hideto Miyabe; Akira Toyoda; Yoshiji Takemoto
SYNLETT, Jul. 2007, [Reviewed] - One-pot amidation of olefins through Pd-catalyzed coupling of alkylboranes and carbamoyl Chlorides
Yoshizumi Yasui; Sayo Tsuchida; Hideto Miyabe; Yoshiji Takemoto
JOURNAL OF ORGANIC CHEMISTRY, Jul. 2007, [Reviewed] - C-N bond formation through amination
Y. Takemoto; H. Miyabe
Comprehensive Organometallic Chemistry III, 2007 - Development of Novel Tandem Bond-Forming Reactions Based on Radical Reactions
Hideto Miyabe
Yakugaku Kenkyu no Shinpo, 2007, [Reviewed], [Invited] - Enantioselective radical cyclizations: A new approach to stereocontrol of cascade reactions
Hideto Miyabe; Yoshiji Takemoto
CHEMISTRY-A EUROPEAN JOURNAL, 2007, [Reviewed], [Invited] - The amino Thiourea-catalyzed asymmetric nucleophilic reactions
Yoshiji Takemoto; Hideto Miyabe
CHIMIA, 2007, [Reviewed], [Invited] - Gold-catalyzed cyclization reaction of alkynyl O-tert-butylcarbamates
H. Miyabe; Y. Sami; T. Naito; Y. Takemoto
Heterocycles, 2007, [Reviewed], [Invited] - Catalytic enantioselective petasis-type reaction of quinolines catalyzed by a newly designed thiourea catalyst
Y. Yamaoka; H. Miyabe; Y. Takemoto
Journal of the American Chemical Society, 2007, [Reviewed] - Reaction of nitroorganic compounds using thiourea catalysts anchored to polymer support
Hideto Miyabe; Sayo Tuchida; Masashige Yamauchi; Yoshiji Takemoto
Synthesis, Oct. 2006, [Reviewed] - Reactive ketimino radical acceptors: Intermolecular alkyl radical addition to imines with a phenolic hydroxyl group
H. Miyabe; Y. Yamaoka; Y. Takemoto
Journal of Organic Chemistry, Mar. 2006, [Reviewed] - Enantioselective cascade radical addition-cyclization-trapping reactions
Hideto Miyabe; Ryuta Asada; Akira Toyoda; Yoshiji Takemoto
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, [Reviewed] - Enantioselective tandem Michael reaction to nitroalkene catalyzed by bifunctional thiourea: total synthesis of (-)-epibatidine
Y Hoashi; T Yabuta; P Yuan; H Miyabe; Y Takemoto
TETRAHEDRON, Jan. 2006, [Reviewed] - Bifunctional-thiourea-catalyzed diastereo- and enantioselective aza-Henry reaction
XN Xu; T Furukawa; T Okino; H Miyabe; Y Takemoto
CHEMISTRY-A EUROPEAN JOURNAL, Dec. 2005, [Reviewed] - Selective synthesis of allylated oxime ethers and nitrones based on palladium-catalyzed allylic substitution of oximes
H. Miyabe; K. Yoshida; V.K. Reddy; A. Matsumura; Y. Takemoto
Journal of Organic Chemistry, Jul. 2005, [Reviewed] - Triethylborane-induced intermolecular radical addition to ketimines
H Miyabe; Y Yamaoka; Y Takemoto
JOURNAL OF ORGANIC CHEMISTRY, Apr. 2005, [Reviewed] - Hydroxylamines as oxygen atom nucleophiles in transition-metal-catalyzed allylic substitution
H. Miyabe; K. Yoshida; M. Yamauchi; Y. Takemoto
Journal of Organic Chemistry, Mar. 2005, [Reviewed] - Zinc-mediated carbon radical addition to glyoxylic imines in aqueous media for the synthesis of α-amino acids
Masafumi Ueda; Hideto Miyabe; Hisako Sugino; Takeaki Naito
Org. Biomol. Chem., 2005, [Reviewed] - Synthesis of α,α-disubstituted amino acids based on tandem reaction of dehydroamino acid derivatives
Hideto Miyabe; Ryuta Asada; Yoshiji Takemoto
Tetrahedron, Jan. 2005, [Reviewed] - Regio- and Stereocontrolled Palladium- or Iridium-Catalyzed Allylation
Yoshiji Takemoto; Hideto Miyabe
Synlett, 2005, [Reviewed], [Invited] - Tandem radical-addition-aldol-type reaction of an α,β- unsaturated oxime ether
Ueda M; Miyabe H; Sugino H; Miyata O; Naito T
Angewandte Chemie - International Edition, 2005, [Reviewed] - Diastereoselective intermolecular radical addition to nitrones
Ueda M; Miyabe H; Teramachi M; Miyata O; Naito T
Journal of Organic Chemistry, 2005, [Reviewed] - Utility of the iridium complex of the pybox ligand in regio- and enantioselective allylic substitution
H. Miyabe; A. Matsumura; K. Moriyama; Y. Takemoto
Organic Letters, Nov. 2004, [Reviewed] - Aqueous medium radical addition to ketimines with a phenolic hydroxyl group
H Miyabe; Y Yamaoka; Y Takemoto
SYNLETT, Nov. 2004, [Reviewed] - Indium as a radical initiator in aqueous media: intermolecular alkyl radical addition to C=N and C=C bond
Hideto Miyabe; Masafumi Ueda; Azusa Nishimura; Takeaki Naito
Tetrahedron, May 2004, [Reviewed] - Palladium or iridium-catalyzed allylic substitution of guanidines having electron-withdrawing substituents
Miyabe, H; Matsumura, A; Yoshida, K; Yamauchi, M; Takemmoto, Y
LETTERS IN ORGANIC CHEMISTRY, Apr. 2004, [Reviewed] - Palladium−Indium Iodide-Mediated Allylation and Propargylation of Glyoxylic Oxime Ether and Hydrazone: The Role of Water in Directing the Diastereoselective Allylation
Hideto Miyabe; Yousuke Yamaoka; Takeaki Naito; Yoshiji Takemoto
The Journal of Organic Chemistry, Jan. 2004, [Reviewed] - Free Radical-Mediated Tandem Reaction of Dehydroamino Acid Derivative with π-Allyl Palladium Complex: Synthesis of α,α-Disubstituted Amino Acids
Yoshiji Takemoto; Hideto Miyabe; Ryuta Asada; Kazumasa Yoshida
Synlett, 2004, [Reviewed] - Solid-Phase Tandem Radical Addition-Cyclization Reaction: Triethylborane-Induced Reaction of Oxime Ethers Anchored to Polymer Support
Hideto Miyabe; Hirotaka Tanaka; Takeaki Naito
Chemical and Pharmaceutical Bulletin, 2004, [Reviewed] - Novel Synthesis of O-Allylated Oxime Ethers Based on Allylic Substitution with Oximes
Yoshiji Takemoto; Hideto Miyabe; Akira Matsumura; Kazumasa Yoshida; Masashige Yamauchi
Synlett, 2004, [Reviewed] - Carbon-Carbon Bond Construction Based on Radical Addition to C=N Bond
Takeaki Naito; Hideto Miyabe; Masafumi Ueda
Synlett, 2004, [Reviewed], [Invited] - The utility of indium in aqueous medium radical reactions
Hideto Miyabe; Takeaki Naito
Organic & Biomolecular Chemistry, 2004, [Reviewed] - Stannyl radical addition-cyclization of oxime ethers connected with olefins
H Miyabe; H Tanaka; T Naito
CHEMICAL & PHARMACEUTICAL BULLETIN, Jan. 2004, [Reviewed] - Zinc-mediated radical reaction of glyoxylic oxime ether and hydrazone in aqueous media: asymmetric synthesis of α-amino acids
Masafumi Ueda; Hideto Miyabe; Azusa Nishimura; Hisako Sugino; Takeaki Naito
Tetrahedron: Asymmetry, Oct. 2003, [Reviewed] - Indium-Mediated Tandem Radical Addition−Cyclization-Trap Reactions in Aqueous Media
Masafumi Ueda; Hideto Miyabe; Azusa Nishimura; Okiko Miyata; Yoshiji Takemoto; Takeaki Naito
Organic Letters, Sep. 2003, [Reviewed] - Synthesis of beta-substituted alpha-amino acids with use of iridium-catalyzed asymmetric allylic substitution
T Kanayama; K Yoshida; H Miyabe; T Kimachi; Y Takemoto
JOURNAL OF ORGANIC CHEMISTRY, Aug. 2003, [Reviewed] - Regioselectivity in Palladium−Indium Iodide-Mediated Allylation Reaction of Glyoxylic Oxime Ether and N-Sulfonylimine
Hideto Miyabe; Yousuke Yamaoka; Takeaki Naito; Yoshiji Takemoto
The Journal of Organic Chemistry, Jul. 2003, [Reviewed] - Tandem Carbon−Carbon Bond-Forming Radical Addition-Cyclization Reaction of Oxime Ether and Hydrazone
Hideto Miyabe; Masafumi Ueda; Kayoko Fujii; Azusa Nishimura; Takeaki Naito
The Journal of Organic Chemistry, Jun. 2003, [Reviewed] - Enantio‐ and Diastereoselective Ir‐Catalyzed Allylic Substitutions for Asymmetric Synthesis of Amino Acid Derivatives
Takatoshi Kanayama; Kazumasa Yoshida; Hideto Miyabe; Yoshiji Takemoto
Angewandte Chemie, May 2003, [Reviewed] - オキシムエーテル類の簡便なラジカル反応 (特集 ファインケミカルにおけるラジカル反応--グリーンケミストリーをめざして)
内藤 猛章; 宮部 豪人
ファインケミカル, May 2003, [Invited] - Development of carbon radical addition to imine derivatives
H Miyabe
YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, May 2003, [Reviewed], [Invited] - Carbon–carbon bond construction on solid support: triethylborane-induced radical reactions of oxime ethers
Hideto Miyabe; Azusa Nishimura; Yumi Fujishima; Takeaki Naito
Tetrahedron, Mar. 2003, [Reviewed] - Novel intermolecular carbon radical addition to a nitrone: asymmetric synthesis of α-amino acids
Masafumi Ueda; Hideto Miyabe; Masako Teramachi; Okiko Miyata; Takeaki Naito
Chemical Communications, Jan. 2003, [Reviewed] - Synthesis of Aminocyclohexitol via Carbon-Carbon Bond-Forming Radical Cyclization of Oxime Ether.
Hideto Miyabe; Akiyoshi Nishiki; Takeaki Naito
Chemical and Pharmaceutical Bulletin, 2003, [Reviewed] - O-Allylic Substitution of Hydroxylamine Derivatives Having an N-Electron-Withdrawing Substituent
Yoshiji Takemoto; Hideto Miyabe; Kazumasa Yoshida; Akira Matsumura; Masashige Yamauchi
Synlett, 2003, [Reviewed] - Enantio- and diastereoselective Ir-catalyzed allylic substitutions for asymmetric synthesis of amino acid derivatives
T Kanayama; K Yoshida; H Miyabe; Y Takemoto
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, [Reviewed] - Diastereoselective Solid-Phase Radical Addition to Oxime Ether Anchored to Polymer Support
Hideto Miyabe; Chihiro Konishi; Takeaki Naito
Chemical and Pharmaceutical Bulletin, 2003, [Reviewed] - Synthesis of Azacycles Basedon Iridium-Catalyzed Sequential Allylic Amination
Yoshiji Takemoto; Hideto Miyabe; Kazumasa Yoshida; Yusuke Kobayashi; Akira Matsumura
Synlett, 2003, [Reviewed] - Radical addition to oxime ethers for asymmetric synthesis of β-amino acid derivatives
Hideto Miyabe; Kayoko Fujii; Takeaki Naito
Organic & Biomolecular Chemistry, Dec. 2002, [Reviewed] - Heterocycle synthesis via radical addition-cyclization of oxime ethers
H Miyabe; O Miyata; T Naito
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Nov. 2002, [Reviewed], [Invited] - Crotylations of α-Carbonyl Radicals with Crotylstannane
Mukund P. Sibi; Hideto Miyabe
Organic Letters, Sep. 2002, [Reviewed] - BF3-promoted hydrostannation of N-heteroatom-substituted imines for the reduction of C=N bond
Masafumi Ueda; Hideto Miyabe; Megumi Namba; Toshiki Nakabayashi; Takeaki Naito
Tetrahedron Letters, Jun. 2002, [Reviewed] - キレーション効果を利用したC-HおよびC-C結合の触媒的活性化 宮部豪人
化学, 2002, [Invited] - Asymmetric synthesis of alpha-amino acids: indium-mediated reactions of glyoxylic oxime ether in aqueous media
H Miyabe; A Nishimura; M Ueda; T Naito
CHEMICAL COMMUNICATIONS, 2002, [Reviewed] - Indium-Mediated Intermolecular Alkyl Radical Addition to Electron-Deficient C=N Bond and C=C Bond in Water
Hideto Miyabe; Masafumi Ueda; Azusa Nishimura; Takeaki Naito
Organic Letters, Dec. 2001, [Reviewed] - Highly diastereoselective radical addition–cyclization strategy: facile synthesis of substituted furans
Mukund P. Sibi; Tara R. Rheault; Hideto Miyabe; Kalyani Patil; Craig P. Jasperse
Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry, Jul. 2001, [Reviewed] - Solid-phase tandem radical addition–cyclisation reaction of oxime ethers
Hideto Miyabe; Kayoko Fujii; Hirotaka Tanaka; Takeaki Naito
Chemical Communications, 2001, [Reviewed] - Development of reaction using imines as a radical acceptor and its stereocontrol
H Miyabe; T Naito
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, Jan. 2001, [Reviewed], [Invited] - A New Alternative to the Mannich Reaction: Tandem Radical Addition−Cyclization Reaction for Asymmetric Synthesis of γ-Butyrolactones and β-Amino Acids
Hideto Miyabe; Kayoko Fujii; Takuya Goto; Takeaki Naito
Organic Letters, Nov. 2000, [Reviewed] - Free-radical reaction of imine derivatives in water
H Miyabe; M Ueda; T Naito
JOURNAL OF ORGANIC CHEMISTRY, Aug. 2000, [Reviewed] - Asymmetric alpha-alkylation of alpha-amino esters using pyridoxal derivatives having a chiral ansa-structure and a chiral ionophore function: a novel example of double asymmetric induction
K Miyashita; H Miyabe; K Tai; H Iwaki; T Imanishi
TETRAHEDRON, Jun. 2000, [Reviewed] - Stereocontrol in Solid-Phase Radical Reactions: Radical Addition to Oxime Ether Anchored to Polymer Support
Hideto Miyabe; Chihiro Konishi; Takeaki Naito
Organic Letters, Apr. 2000, [Reviewed] - Reactions of Alkyl Radicals with Oxime Ether: One-Pot Synthesis of α-Amino Acids
Hideto Miyabe; Masafumi Ueda; Naoko Yoshioka; Kumiko Yamakawa; Takeaki Naito
Tetrahedron, Apr. 2000, [Reviewed] - N-Sulfonylimines as an excellent acceptor for intermolecular radical reactions
Hideto Miyabe; Masafumi Ueda; Takeaki Naito
Chemical Communications, 2000, [Reviewed] - Development of Solid-Phase Radical Reactions Using Oxime Ethers as a Radical Acceptor
Hideto MIYABE
YAKUGAKU ZASSHI, 2000, [Reviewed], [Invited] - Asymmetric Synthesis of α-Amino Acids Based on Carbon Radical Addition to Glyoxylic Oxime Ether
Hideto Miyabe; Chikage Ushiro; Masafumi Ueda; Kumiko Yamakawa; Takeaki Naito
The Journal of Organic Chemistry, Dec. 1999, [Reviewed] - Triethylborane-induced solid-phase radical cyclization of oxime ethers
Hideto Miyabe; Hirotaka Tanaka; Takeaki Naito
Tetrahedron Letters, Nov. 1999, [Reviewed] - Chiral environment specifically induced by metal ion: Asymmetric α-alkylation of α-amino esters using pyridoxal derivatives having a chiral ionophore function
Kazuyuki Miyashita; Hideto Miyabe; Kuninori Tai; Chiaki Kurozumi; Hiroshi Iwaki; Takeshi Imanishi
Tetrahedron, Oct. 1999, [Reviewed] - Alkylative amination of aldehydes via carbon-carbon bond formation based on radical addition to carbon-nitrogen double bond
Hideto Miyabe; Kumiko Yamakawa; Naoko Yoshioka; Takeaki Naito
Tetrahedron, Sep. 1999, [Reviewed] - Highly Diastereoselective Radical Addition to Oxime Ethers: Asymmetric Synthesis of β-Amino Acids
Hideto Miyabe; Kayoko Fujii; Takeaki Naito
Organic Letters, Jul. 1999, [Reviewed] - Carbon Radical Addition to Glyoxylic Oxime Ether via Iodine Atom-Transfer Process
Hideto Miyabe; Masafumi Ueda; Naoko Yoshioka; Takeaki Naito
Synlett, Apr. 1999, [Reviewed] - Novel Synthesis of α-Amino Acid Derivatives through Triethylborane-Induced Solid-Phase Radical Reactions
Hideto Miyabe; Yumi Fujishima; Takeaki Naito
The Journal of Organic Chemistry, Mar. 1999, [Reviewed] - Intermolecular alkyl radical addition to the carbon-nitrogen double bond of oxime ethers and hydrazones
Hideto Miyabe; Ryouhei Shibata; Masato Sangawa; Chikage Ushiro; Takeaki Naito
Tetrahedron, Sep. 1998, [Reviewed] - Total Synthesis of (−)-Balanol
Hideto Miyabe; Mayumi Torieda; Kyoko Inoue; Kazumi Tajiri; Toshiko Kiguchi; Takeaki Naito
The Journal of Organic Chemistry, Jun. 1998, [Reviewed] - Samarium diiodide-induced radical cyclization of oxime ether connected with formyl group: Synthesis of 4-pyrimidinyl- and 4-purinylpyrrolidin-3-ol nucleoside analogues
Hideto Miyabe; Sayaka Kanehira; Kaori Kume; Hiromi Kandori; Takeaki Naito
Tetrahedron, May 1998, [Reviewed] - Carbon-carbon bond formation via intermolecular carbon radical addition to aldoxime ethers
Hideto Miyabe; Ryouhei Shibata; Chikage Ushiro; Takeaki Naito
Tetrahedron Letters, Feb. 1998, [Reviewed] - One-pot synthesis of α-amino acids based on free radical-mediated carbon–carbon bond formation
Hideto Miyabe; Naoko Yoshioka; Masafumi Ueda; Takeaki Naito
Journal of the Chemical Society, Perkin Transactions 1, 1998, [Reviewed] - Total Synthesis of (-)-Balanol
Hideto Miyabe; Mayumi Torieda; Toshiko Kiguchi; Takeaki Naito
Synlett, May 1997, [Reviewed] - Synthesis of Several 3-Substituted 2-Trifluoromethylinodoles via Mannich Reaction of 2-Trifluoromethylindoles.
Kazuyuki MIYASHITA; Katsunori KONDOH; Katsutoshi TSUCHIYA; Hideto MIYABE; Takeshi IMANISHI
Chemical and Pharmaceutical Bulletin, 1997, [Reviewed] - Highly diastereoselective radical addition to glyoxylic oxime ether: asymmetric synthesis of α-amino acids
Hideto Miyabe; Chikage Ushiro; Takeaki Naito
Chemical Communications, 1997, [Reviewed] - α-alkylation of α-amino esters by using a pyridoxal model compound having a Li+-ionophore character
Kazuyuki Miyashita; Hideto Miyabe; Chiaki Kurozumi; Kuninori Tai; Takeshi Imanishi
Tetrahedron, Sep. 1996, [Reviewed] - Asymmetric α-alkylation of α-amino esters using pyridoxal model compounds with a chiral ionophore function; dependence of stereoselectivity on a chelated metal ion
Kazuyuki Miyashita; Hideto Miyabe; Kuninori Tai; Chiaki Kurozumi; Takeshi Imanishi
Chem. Commun., 1996, [Reviewed] - Novel indole-ring formation by thermolysis of 2-(N-acylamino)-benzylphosphonium salts. Effective synthesis of 2-trifluoromethylindoles
Kazuyuki Miyashita; Katsunori Kondoh; Katsutoshi Tsuchiya; Hideto Miyabe; Takeshi Imanishi
Journal of the Chemical Society, Perkin Transactions 1, 1996, [Reviewed] - Novel Indore-Ring Construction Method for the Synthesis of 2-Trifluoromethylidoles
Takeshi Imanishi; Kazuyuki Miyashita; Katsutoshi Tsuchiya; Katsunori Kondoh; Hideto Miyabe
HETEROCYCLES, 1996, [Reviewed] - Diastereoselective Reduction of α-(p-Tolylsulfinyl)ketoximes
Kazuyuki Miyashita; Tomohiro Toyoda; Hideto Miyabe; Takeshi Imanishi
Synlett, Dec. 1995, [Reviewed] - Efficient α-Alkylation of α-Amino Acids by Means of a Novel Pyridoxal Model Compound
Kazuyuki Miyashita; Hideto Miyabe; Chiaki Kurozumi; Takeshi Imanishi
Chemistry Letters, Jun. 1995, [Reviewed]
MISC
- Tandem radical-addition-aldol-type reaction of an α,β- unsaturated oxime ether
Masafumi Ueda; Hideto Miyabe; Hisako Sugino; Okiko Miyata; Takeaki Naito
Angewandte Chemie - International Edition, 26 Sep. 2005 - Selective synthesis of allylated oxime ethers and nitrones based on palladium-catalyzed allylic substitution of oximes
Hideto Miyabe; Kazumasa Yoshida; Valluru Krishna Reddy; Akira Matsumura; Yoshiji Takemoto
Journal of Organic Chemistry, 08 Jul. 2005 - Diastereoselective Intermolecular Radical Addition to Nitrones. Masafumi Ueda, Hideto Miyabe, Masako Teramachi, Okiko Miyata, Takeaki Naito.
J. Org. Chem., 2005 - Triethylborane-Induced Intermolecular Radical Addition to Ketimines. Hideto Miyabe, Yousuke Yamaoka, Yoshiji Takemoto.
J. Org. Chem., 2005 - Hydroxylamines as Oxygen Atom Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution. Hideto Miyabe, Kazumasa Yoshida, Masashige Yamauchi, Yoshiji Takemoto.
J. Org. Chem., 2005 - Synthesis of α,α-Disubstituted Amino Acids Based on Tandem Reaction of Dehydroamino Acid Derivatives. Hideto Miyabe, Ryuta Asada, Yoshiji Takemoto.
Tetrahedron, 2005 - Zinc-mediated carbon radical addition to glyoxylic imines in aqueous media for the synthesis of alpha-amino acids
M Ueda; H Miyabe; H Suginoa; T Naito
ORGANIC & BIOMOLECULAR CHEMISTRY, 2005 - Tandem Radical-Addition-Aldol-Type Reaction of an α,β-Unsaturated Oxime Ether. Masafumi Ueda, Hideto Miyabe, Hisako Sugino, Okiko Miyata, Takeaki Naito.
Angwen. Chem., Int. Ed., 2005 - Diastereoselective Intermolecular Radical Addition to Nitrones. Masafumi Ueda, Hideto Miyabe, Masako Teramachi, Okiko Miyata, Takeaki Naito.
J. Org. Chem., 2005 - Triethylborane-Induced Intermolecular Radical Addition to Ketimines. Hideto Miyabe, Yousuke Yamaoka, Yoshiji Takemoto.
J. Org. Chem., 2005 - Hydroxylamines as Oxygen Atom Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution. Hideto Miyabe, Kazumasa Yoshida, Masashige Yamauchi, Yoshiji Takemoto.
J. Org. Chem., 2005 - Synthesis of α,α-disubstituted amino acids based on tandem reaction of dehydroamino acid derivatives
Hideto Miyabe; Ryuta Asada; Yoshiji Takemoto
Tetrahedron, Jan. 2005 - Zinc-mediated carbon radical addition to glyoxylic imines in aqueous media for the synthesis of alpha-amino acids
M Ueda; H Miyabe; H Suginoa; T Naito
ORGANIC & BIOMOLECULAR CHEMISTRY, 2005 - Regio- and Stereocontrolled Palladium- or Iridium-Catalyzed Allylation
Yoshiji Takemoto; Hideto Miyabe
Synlett, 2005, [Reviewed], [Invited] - Novel synthesis of O-allylated oxime ethers based on allylic substitution with oximes
H Miyabe; A Matsumura; K Yoshida; M Yamauchi; Y Takemoto
SYNLETT, Oct. 2004 - Solid-phase tandem radical addition-cyclization reaction: Triethylborane-induced reaction of oxime ethers anchored to polymer support
H Miyabe; H Tanaka; T Naito
CHEMICAL & PHARMACEUTICAL BULLETIN, Jul. 2004 - Carbon-carbon bond construction based on radical addition to C=N bond
H Miyabe; M Ueda; T Naito
SYNLETT, Jun. 2004 - Indium as a radical initiator in aqueous media: intermolecular alkyl radical addition to C=N and C=C bond
H Miyabe; M Ueda; A Nishimura; T Naito
TETRAHEDRON, May 2004 - Free Radical-Mediated Tandem Reaction of Dehydroamino Acid Derivative with π-Allyl Palladium Complex: Synthesis of α,α-Disubstituted Amino Acids
Hideto Miyabe; Ryuta Asada; Kazumasa Yoshida; Yoshiji Takemoto
Synlett, 18 Feb. 2004 - Free Radical-Mediated Tandem Reaction of Dehydroamino Acid Derivative with π-Allyl Palladium Complex: Synthesis of α,α-Disubstituted Amino Acids
Hideto Miyabe; Ryuta Asada; Kazumasa Yoshida; Yoshiji Takemoto
Synlett, 18 Feb. 2004 - Palladium-indium iodide-mediated allylation and propargylation of glyoxylic oxime ether and hydrazone: The role of water in directing the diastereoselective allylation
H Miyabe; Y Yamaoka; T Naito; Y Takemoto
JOURNAL OF ORGANIC CHEMISTRY, Feb. 2004 - The utility of indium in aqueous medium radical reactions
H Miyabe; T Naito
ORGANIC & BIOMOLECULAR CHEMISTRY, 2004 - Stannyl radical addition-cyclization of oxime ethers connected with olefins
Hideto Miyabe; Hirotaka Tanaka; Takeaki Naito
Chemical and Pharmaceutical Bulletin, Jan. 2004 - Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines Having Electron-Withdrawing Substituents Hideto Miyabe, Akira Matsumura, Kazumasa Yoshida, Masashige Yamauchi, Yoshiji Takemoto.
Lett. Org. Chem, 2004 - Aqueous-Medium Radical Addition to Ketimines Having Phenolic Hydroxyl Group Hideto Miyabe, Yousuke Yamaoka, Yoshiji Takemoto.
Synlett, 2004 - Utility of the Iridium-Complexr of the Pybox Ligand in Regio- and Enantioselective Allylic Substitutions Hideto Miyabe, Akira Matsumura, Katsuhiko Moriyama, Yoshiji Takemoto.
Org Lett, 2004 - The Utility of Indium in Aqueous Medium Radical Reactions. Hideto Miyabe, Takeaki Naito.
Org. Biomol. Chem., 2004 - Carbon-Carbon Bond Construction Based on Radical Addition to C=N Bond. Hideto Miyabe, Masafumi Ueda, Takeaki Naito.
Synlett, 2004 - Stanny Radical Addition-Cyclization of Oxime Ethers Connected with Olefin Moieties Hideto Miyabe, Hirotaka Tanaka, Takeaki Naito.
Chem. Pharm. Bull, 2004 - Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines Having Electron-Withdrawing Substituents Hideto Miyabe, Akira Matsumura, Kazumasa Yoshida, Masashige Yamauchi, Yoshiji Takemoto.
Lett. Org. Chem, 2004 - Aqueous-Medium Radical Addition to Ketimines Having Phenolic Hydroxyl Group Hideto Miyabe, Yousuke Yamaoka, Yoshiji Takemoto.
Synlett, 2004 - Utility of the Iridium-Complexr of the Pybox Ligand in Regio- and Enantioselective Allylic Substitutions Hideto Miyabe, Akira Matsumura, Katsuhiko Moriyama, Yoshiji Takemoto.
Org Lett, 2004 - Carbon-Carbon Bond Construction Based on Radical Addition to C=N Bond Hideto Miyabe, Masafumi Ueda, Takeaki Naito.
Synlett, 2004 - The Utility of Indium in Aqueous Medium Radical Reactions Hideto Miyabe, Takeaki Naito.
Org Biomol. Chem, 2004 - Zinc-mediated radical reaction of glyoxylic oxime ether and hydrazone in aqueous media: asymmetric synthesis of alpha-amino acids
M Ueda; H Miyabe; A Nishimura; H Sugino; T Naito
TETRAHEDRON-ASYMMETRY, Oct. 2003 - Zinc-mediated radical reaction of glyoxylic oxime ether and hydrazone in aqueous media: asymmetric synthesis of alpha-amino acids
M Ueda; H Miyabe; A Nishimura; H Sugino; T Naito
TETRAHEDRON-ASYMMETRY, Oct. 2003 - Indium-mediated tandem radical addition-cyclization-trap reactions in aqueous media
M Ueda; H Miyabe; A Nishimura; O Miyata; Y Takemoto; T Naito
ORGANIC LETTERS, Oct. 2003 - Synthesis of β-substituted α-amino acids with use of iridium-catalyzed asymmetric allylic substitution
Takatoshi Kanayama; Kazumasa Yoshida; Hideto Miyabe; Tetsutaro Kimachi; Yoshiji Takemoto
Journal of Organic Chemistry, 08 Aug. 2003 - Regioselectivity in palladium-indium iodide-mediated allylation reaction of glyoxylic oxime ether and N-sulfonylimine
H Miyabe; Y Yamaoka; T Naito; Y Takemoto
JOURNAL OF ORGANIC CHEMISTRY, Aug. 2003 - Tandem carbon-carbon bond-forming radical addition-cyclization reaction of oxime ether and hydrazone
H Miyabe; M Ueda; K Fujii; A Nishimura; T Naito
JOURNAL OF ORGANIC CHEMISTRY, Jul. 2003 - Synthesis of azacycles based on iridium-catalyzed sequential allylic amination
H Miyabe; K Yoshida; Y Kobayashi; A Matsumura; Y Takemoto
SYNLETT, Jun. 2003 - Diastereoselective solid-phase radical addition to oxime ether anchored to polymer support
H Miyabe; C Konishi; T Naito
CHEMICAL & PHARMACEUTICAL BULLETIN, May 2003 - O-allylic substitution of hydroxylamine derivatives having an N-electron-withdrawing substituent
H Miyabe; K Yoshida; A Matsumura; M Yamauchi; Y Takemoto
SYNLETT, Mar. 2003 - Carbon-carbon bond construction on solid support: triethylborane-induced radical reactions of oxime ethers
H Miyabe; A Nishimura; Y Fujishima; T Naito
TETRAHEDRON, Mar. 2003 - Synthesis of aminocyclohexitol via carbon-carbon bond-forming radical cyclization of oxime ether
H Miyabe; A Nishiki; T Naito
CHEMICAL & PHARMACEUTICAL BULLETIN, Jan. 2003 - Novel intermolecular carbon radical addition to a nitrone: asymmetric synthesis of alpha-amino acids
M Ueda; H Miyabe; M Teramachi; O Miyata; T Naito
CHEMICAL COMMUNICATIONS, 2003 - Radical addition to oxime ethers for asymmetric synthesis of beta-amino acid derivatives
H Miyabe; K Fujii; T Naito
ORGANIC & BIOMOLECULAR CHEMISTRY, Jan. 2003 - Synthesis of aminocyclohexitol via carbon-carbon bond-forming radical cyclization of oxime ether
Hideto Miyabe; Akiyoshi Nishiki; Takeaki Naito
Chemical and Pharmaceutical Bulletin, Jan. 2003 - Intermolecular Carbon Radical Addition to Nitrone: The Asymmetric Synthesis of α-Amino Acids Masafumi Ueda, Hideto Miyabe, Masako Teramachi, Okiko Miyata, Takeaki Naito.
Chem. Commun., 2003 - Radical addition to oxime ethers for asymmetric synthesis of beta-amino acid derivatives
H Miyabe; K Fujii; T Naito
ORGANIC & BIOMOLECULAR CHEMISTRY, Jan. 2003 - O-Allylic Substitution of Hydroxylamine Derivatives Having an N-Electron-Withdrawing Substituent Hideto Miyabe, Kazumasa Yoshida, Akira Matsumura, Masashige Yamaguchi, yoshiji Takemoto.
Synlett, 2003 - Enantio- and diastereoselective Ir-catalyzed allylic substitutions for asymmetric synthesis of amino acid derivatives
T Kanayama; K Yoshida; H Miyabe; Y Takemoto
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003 - Synthesis of β-Substituted α-Amino Acids with Use of Iridium-Catalyzed Asymmetric Allylic Substitution Takatoshi Kanayama, Kazumasa Yoshida, Hideto Miyabe, Tetsutaro Kimachi, and Yoshiji Takemoto.
J. Org. Chem., 2003 - Regioselectivity in Palladium-Indium Iodide-Mediated Allylation Reaction of Glyoxylic Oxime Ether and N-Sulfonylimine Hideto Miyabe, Yousuke Yamaoka, Takeaki Naito, Yoshiji Takemoto.
J. Org. Chem., 2003 - Crotylations of alpha-carbonyl radicals with crotylstannane
MP Sibi; H Miyabe
ORGANIC LETTERS, Oct. 2002 - BF3-promoted hydrostannation of N-heteroatom-substituted imines for the reduction of C=N bond
M Ueda; H Miyabe; M Namba; T Nakabayashi; T Naito
TETRAHEDRON LETTERS, Jun. 2002 - Asymmetric Synthesis of a-Amino Acids: Indium-Mediated Reactions of Glyoxylic Oxime Ether in Aqueous Media. Hideto Miyabe, Azusa Nishimura, Masafumi Ueda, Takeaki Naito.
Chem. Commun., 2002 - Indium-mediated intermolecular alkyl radical addition to electron-deficient C=N bond and C=C bond in water
H Miyabe; M Ueda; A Nishimura; T Naito
ORGANIC LETTERS, Jan. 2002 - Asymmetric Synthesis of a-Amino Acids: Indium-Mediated Reactions of Glyoxylic Oxime Ether in Aqueous Media. Hideto Miyabe, Azusa Nishimura, Masafumi Ueda, Takeaki Naito.
Chem. Commun., 2002 - Solid-Phase Tandem Radical Addition-Cyclisation Reaction of Oxime Ethers. Hideto Miyabe, Kayoko Fujii, Hirotaka Tanaka, Takeaki Naito.
Chem. Commun., 2001 - Highly Diastereoselective Radical Addition-Cyclization Strategy: Facile Synthesis of Substituted Furans. Mukund P. Sibi, Tara R. Rheault, Hideto Miyabe, Kalyani Patil, Craig P. Jasperse.
C. R. Acad. Sci. Paris, Chimie, 2001 - Highly Diastereoselective Radical Addition-Cyclization Strategy: Facile Synthesis of Substituted Furans. Mukund P. Sibi, Tara R. Rheault, Hideto Miyabe, Kalyani Patil, Craig P. Jasperse.
C. R. Acad. Sci. Paris, Chimie, 2001 - Stereocontrol in solid-phase radical reactions: Radical addition to oxime ether anchored to polymer support
H Miyabe; C Konishi; T Naito
ORGANIC LETTERS, May 2000 - Reactions of alkyl radicals with oxime ether: One-pot synthesis of α- amino acids
Hideto Miyabe; Masafumi Ueda; Naoko Yoshioka; Kumiko Yamakawa; Takeaki Naito
Tetrahedron, 14 Apr. 2000 - Asymmetric synthesis of α-amino acids based on carbon radical addition to glyoxylic oxime ether
Hideto Miyabe; Chikage Ushiro; Masafumi Ueda; Kumiko Yamakawa; Takeaki Naito
Journal of Organic Chemistry, 14 Jan. 2000 - Free Radical Reaction of Imine Derivatives in Water. Hideto Miyabe, Masafumi Ueda, Takeaki Naito.
J. Org. Chem., 2000 - A New Alternative to Mannich Reaction: Tandem Radical Addition-Cyclization Reaction for Asymmetric Synthesis of g-Butyrolactones and b-Amino Acids. Hideto Miyabe, Kayoko Fujii, Takuya Goto, Takeaki Naito.
Org. Lett., 2000 - Free Radical Reaction of Imine Derivatives in Water. Hideto Miyabe, Masafumi Ueda, Takeaki Naito.
J. Org. Chem., 2000 - Asymmetric synthesis of alpha-amino acids based on carbon radical addition to glyoxylic oxime ether
H Miyabe; C Ushiro; M Ueda; K Yamakawa; T Naito
JOURNAL OF ORGANIC CHEMISTRY, Jan. 2000 - Triethylborane-induced solid-phase radical cyclization of oxime ethers
H Miyabe; H Tanaka; T Naito
TETRAHEDRON LETTERS, Nov. 1999 - Chiral environment specifically induced by metal ion: Asymmetric alpha-alkylation of alpha-amino esters using pyridoxal derivatives having a chiral ionophore function
K Miyashita; H Miyabe; K Tai; C Kurozumi; H Iwaki; T Imanishi
TETRAHEDRON, Oct. 1999 - Chiral environment specifically induced by metal ion: Asymmetric alpha-alkylation of alpha-amino esters using pyridoxal derivatives having a chiral ionophore function
K Miyashita; H Miyabe; K Tai; C Kurozumi; H Iwaki; T Imanishi
TETRAHEDRON, Oct. 1999 - Alkylative amination of aldehydes via carbon-carbon bond formation based on radical addition to carbon-nitrogen double bond
H Miyabe; K Yamakawa; N Yoshioka; T Naito
TETRAHEDRON, Sep. 1999 - Novel synthesis of α-amino acid derivatives through triethylborane- induced solid-phase radical reactions
Hideto Miyabe; Yumi Fujishima; Takeaki Naito
Journal of Organic Chemistry, 02 Apr. 1999 - Carbon radical addition to glyoxylic oxime ether via iodine atom-transfer process
H Miyabe; M Ueda; N Yoshioka; T Naito
SYNLETT, Apr. 1999 - Novel synthesis of alpha-amino acid derivatives through triethylborane-induced solid-phase radical reactions
H Miyabe; Y Fujishima; T Naito
JOURNAL OF ORGANIC CHEMISTRY, Apr. 1999 - Highly Diastereoselective Radical Addition to Oxime Ethers: Asymmetric Synthesis of b-Amino Acids. Hideto Miyabe, Kayoko Fujii, Takeaki Naito.
Org. Lett., 1999 - Novel Synthesis of a-Amino Acid Derivatives Through Triethylborane-Induced Solid-Phase Radical Reactions. Hideto Miyabe, Yumi Fujishima, Takeaki Naito.
J. Org. Chem., 1999 - Intermolecular alkyl radical addition to the carbon-nitrogen double bond of oxime ethers and hydrazones
H Miyabe; R Shibata; M Sangawa; C Ushiro; T Naito
TETRAHEDRON, Sep. 1998 - Samarium diiodide-induced radical cyclization of oxime ether connected with formyl group: Synthesis of 4-pyrimidinyl- and 4-purinylpyrrolidin-3-ol nucleoside analogues
H Miyabe; S Kanehira; K Kume; H Kandori; T Naito
TETRAHEDRON, May 1998 - Carbon-carbon bond formation via intermolecular carbon radical addition to aldoxime ethers
H Miyabe; R Shibata; C Ushiro; T Naito
TETRAHEDRON LETTERS, Feb. 1998 - Total Synthesis of (-)-Balanol. Hideto Miyabe, Mayumi Torieda, Kyoko Inoue, Kazumi Tajiri, Toshiko Kiguchi, Takeaki Naito.
J. Org. Chem., 1998 - Total Synthesis of (-)-Balanol. Hideto Miyabe, Mayumi Torieda, Kyoko Inoue, Kazumi Tajiri, Toshiko Kiguchi, Takeaki Naito.
J. Org. Chem., 1998 - One-Pot Synthesis of a-Amino Acids Based on Free Radical-Mediated Carbon-Carbon Bond Formation. Hideto Miyabe, Naoko Yoshioka, Masafumi Ueda, Takeaki Naito.
J. Chem. Soc., Perkin Trans. 1, 1998 - Synthesis of several 3-substituted 2-trifluoromethylindoles via Mannich reaction of 2-trifluoromethylindoles
Kazuyuki Miyashita; Katsunori Kondoh; Katsutoshi Tsuchiya; Hideto Miyabe; Takeshi Imanishi
Chemical and Pharmaceutical Bulletin, 1997 - Total Synthesis of (-)-Balanol. Hideto Miyabe, Mayumi Torieda, Toshiko Kiguchi, Takeaki Naito.
Synlett, 1997 - Highly Diastereoselective Radical Addition to Glyoxylic Oxime Ether: Asymmetric Synthesis of a-Amino Acids. Hideto Miyabe, Chikage Ushiro, Takeaki Naito.
Chem. Commun., 1997 - Synthesis of Several 3-Substituted 2-Trifluoromethylindoles via Mannich Reaction of 2-Trifluoromethylindoles. Kazuyuki Miyashita, Katsunori Kondoh, Katsutoshi Tsuchiya, Hideto Miyabe, Takeshi Imanishi.
Chem. Pharm. Bull., 1997 - Total Synthesis of (-)-Balanol. Hideto Miyabe, Mayumi Torieda, Toshiko Kiguchi, Takeaki Naito.
Synlett, 1997 - α-Alkylation of α-amino esters by using a pyridoxal model compound having a Li+-ionophore character
Kazuyuki Miyashita; Hideto Miyabe; Chiaki Kurozumi; Kuninori Tai; Takeshi Imanishi
Tetrahedron, 09 Sep. 1996 - Novel indole-ring formation by thermolysis of 2-(N-acylamino)-benzylphosphonium salts. Effective synthesis of 2-trifluoromethyl-indoles
K Miyashita; K Kondoh; K Tsuchiya; H Miyabe; T Imanishi
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, Jun. 1996 - Novel indole-ring construction method for the synthesis of 2-trifluoromethylindoles
K Miyashita; K Tsuchiya; K Kondoh; H Miyabe; T Imanishi
HETEROCYCLES, Jan. 1996 - Asymmetric α-alkylation of α-amino esters using pyridoxal model compounds with a chiral ionophore function; dependence of stereoselectivity on a chelated metal ion
Kazuyuki Miyashita; Hideto Miyabe; Kuninori Tai; Chiaki Kurozumi; Takeshi Imanishi
Chemical Communications, 1996 - Novel Indole-ring Construction Method for the Synthesis of 2-Trifluoromethylindoles. Kazuyuki Miyashita, Katsutoshi Tsuchiya, Katsunori Kondoh, Hideto Miyabe, Takeaki Imanishi.
Heterocycles, 1996 - Efficient a-Alkylation of a-Amino Acids by Means of a Novel Pyridoxal Model Compound. Kazuyuki Miyashita, Hideto Miyabe, Chiaki Kurozumi, Takeshi Imanishi.
Chem. Lett., 1995 - Diastereoselective Reduction of a-(p-Tolylsulfinyl)ketoximes. Kazuyuki Miyashita, Tomohiro Toyoda, Hideto Miyabe, Takeshi Imanishi.
Synlett, 1995 - Diastereoselective Reduction of a-(p-Tolylsulfinyl)ketoximes. Kazuyuki Miyashita, Tomohiro Toyoda, Hideto Miyabe, Takeshi Imanishi.
Synlett, 1995
Books and other publications
- C-O Bond Formation through Cross-Dehydrogenative Coupling (Chapter 16), Science of Synthesis: Cross-Dehydrogenative Coupling, Ed. Maiti, D.
Hideto Miyabe, Joint work, Vol. 1, pp 493-520
Thieme Chemistry: Stuttgart Germany, 2023, [Reviewed] - Recent Advances in Cooperative N-Heterocyclic Carbene Catalysis (Chapter 2), Carbene. Open access peer-reviewed Edited volume, Eds. Saha, S. and Arunava Manna, A.
Hideto Miyabe, Joint work, pp 1-14
IntechOpen, London, 2022, [Reviewed] - Synthesis of Nitrogen-Heterocycles Based on N-Heterocyclic Carbene Organocatalysis (Chapter 4), More Synthetic Approaches to Nonaromatic Nitrogen Heterocycles, In Volume 1, Ed. Phillips, A. M. F.
Hideto Miyabe, Joint work, pp 163-212
John Wiley & Sons: Hoboken NJ, 2022, [Reviewed] - Enantioselective Synthesis of Nitrogen Heterocycles by Radical Reactions (Chapter 19), Synthetic Approaches to Nonaromatic Nitrogen Heterocycles. In Volume 2, Ed. Phillips, A. M. F.
Hideto Miyabe, Joint work, pp 595-630
2020, [Reviewed] - Catalytic and Enantioselective C-C Bond Forming Radical Reactions, Elsevier Reference Modules in Chemistry, Molecular Sciences and Chemical Engineering, Ed. Reedijk, J.
Hideto Miyabe, Joint work, pp 1-20
Elsevier, Waltham, MA., 2019, [Reviewed] - Organic Reactions Promoted by Metal-Free Organic Dyes under Visible Light Irradiation (Chapter 1), Visible-Light Photocatalysis of Carbon-Based Materials. Open access peer-reviewed Edited volume, Ed. Yao, Y.
Hideto Miyabe, Joint work, pp 1-18
IntechOpen, London, 2018, [Reviewed] - Hydrogen-Bonding Activation in Chiral Organocatalysts (Chapter 1), Recent Advances in Organocatalysis. Ed. Karamé, I.; Srour, H.
Hideto Miyabe, Joint work, pp 3-16
INTECH: Croatia, 2016, [Reviewed] - Cyclization Reactions Promoted by Perfluoroalkyl Radical Additions (Chapter 5), Advances in Chemistry Research, Volume 32. Ed. Taylor, J. C.
Hideto Miyabe, Joint work, pp 123-140
Nova Science Pub Inc: NY, 2016 - Titanium Dioxide-Induced Photocatalytic Reduction for Organic Synthesis, Titanium Dioxide: Chemical Properties, Applications and Environmental Effects. Ed. Brown, J.
Shigeru Kohtani, Hideto Miyabe, Joint work, pp 157-176
Nova Science Pub Inc: NY, 2014 - Progress in Iridium-Catalyzed Allylic Substitutions, Iridium: Occurrence, Characteristics and Applications. Eds. Fukui, C. Ono, M.
Hideto Miyabe, Joint work, pp 113-138
Nova Science Pub Inc: NY, 2012 - Photocatalytic Hydrogenation on Semiconductor Particles, Hydrogenation. Ed. Karamé, I.
Shigeru Kohtani, Eito Yoshioka, Hideto Miyabe, Joint work, pp 291-308
INTECH: Croatia, 2012 - Asymmetric Carbon-Heteroatom Bond-Forming Reactions
Yoshiji Takemoto; Hideto Miyabe
John Wiley and Sons, Mar. 2010, [Reviewed] - β-ラクタム系抗生物質(7.11) 化学構造と薬理作用―医薬品を化学的に読む―
宮部 豪人, Joint work, pp 184-194
廣川書店, 2010 - C-N Bond Formation through Amination (Chapter 10.4.2.), Comprehensive Organometallic Chemistry, 3rd Edition (COMC-III), Volume 10. Applications II: Transition Metal Compounds in Organic Synthesis 1, Eds. Crabtree, R. H.; Mingos, D. M. P.
Yoshiji Takemoto, Hideto Miyabe, Joint work, Vol. 10.15, pp 695-724
Elsevier: Oxford, 2006, [Reviewed]
Affiliated academic society
Research Themes
- Elucidation of crystal plane-selective photoasymmetric hydrogenation reaction on shape-controlled titanium oxide nanocrystals
Grant-in-Aid for Scientific Research (C)
Hyogo University of Health Sciences
01 Apr. 2019 - 31 Mar. 2022 - Development of synthetic reactions based on catalytic generation of radicals
Grant-in-Aid for Scientific Research (C)
Hyogo University of Health Sciences
01 Apr. 2016 - 31 Mar. 2020 - Development of visible-light responsive photocatalysts for degradation of anti-cancer agents
Grant-in-Aid for Scientific Research (C)
Hyogo University of Health Sciences
01 Apr. 2015 - 31 Mar. 2019 - Study on Catalytic Radical Reaction Process
Grant-in-Aid for Scientific Research (C)
Hyogo University of Health Sciences
01 Apr. 2013 - 31 Mar. 2016 - Creation of Innovative Organocatalysts Using the Network of Intermolecular Interactions
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
Kyoto University
01 Apr. 2011 - 31 Mar. 2016 - Preparation of a highly ordered nano-porous photocatalyst and its application to CO2 fixation based on radical chemistry
Grant-in-Aid for Scientific Research (C)
Hyogo University of Health Sciences
01 Apr. 2012 - 31 Mar. 2015 - New deployment of the synthetic method utilized the characteristic of radical species
Grant-in-Aid for Scientific Research (C)
Hyogo University of Health Sciences
01 Apr. 2010 - 31 Mar. 2014 - Development of novel redox coupling reactions using photocatalysts
Grant-in-Aid for Scientific Research (C)
Hyogo University of Health Sciences
2009 - 2011 - Development of hybrid domino reactions via multi-chemical species and the synthetic application
Grant-in-Aid for Scientific Research (B)
Kobe Pharmaceutical University
2008 - 2010 - Development of novel synthesis reactions based on radicals
Grant-in-Aid for Scientific Research (C)
Hyogo University of Health Sciences
2007 - 2009 - 連続ラジカル反応を基盤とした環境調和型反応の開発研究
2008 - ラジカル化学に立脚した生命機能探索分子の創製
2008 - Development of Chiral Organocatalyst and Application to Asymmetric Synthesis
Grant-in-Aid for Scientific Research (B)
KYOTO UNIVERSITY
2004 - 2006 - ラジカル反応を基盤とした新規連続結合形成反応の開拓
2004 - ラジカル種の特性を利用した新規タンデム反応の開発
ラジカル種の特性を利用した新規タンデム反応の開発
2003 - Drug creation involving hybrid type of low molecular weight biomolecules as lead compounds
Grant-in-Aid for Scientific Research (C)
Kobe Pharmaceutical University
2000 - 2002 - 環境調和適応型固相ラジカル反応の開発と複合型アミノ酸類の新規固相合成
2000 - エナンチオ選択的ラジカル環化反応に基づく中員環形成とアスベスチニンの全合成への応用
2000 - 固相ラジカル反応の立体制御と水中固相反応への展開
2000 - Synthesis of Cyclic Amino Acids Aiming at Elucidation of Neurotransmission Mechanism
Grant-in-Aid for Scientific Research (C)
Kobe Pharmaceutical University
1997 - 1999 - ラジカル反応の立体制御と固相合成への展開
1998
